LASER-INDUCED FLUORESCENCE MATRIX STUDY OF 1,3-DIFLUOROBENZENE RADICAL CATION

被引：14

作者：

BONDYBEY, VE

ENGLISH, JH

MILLER, TA

机构：

[1] Bell Telephone Laboratories, Murray Hill

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 66卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80389-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Laser induced fluorescence excitation and resolved emission spectra of 1,3-C6H4F+2 are obtained in a Ne matrix with high signal/noise despite the ion's low emission quantum yield. The ground state vibrational structure is mostly regular but that of the upper is very irregular suggesting nearly degenerate, mutually perturbing, excited states. © 1979.

引用

页码：165 / 168

页数：4

共 10 条

[1] RADIATIVE RELAXATION OF B(PI-1) EXCITED ELECTRONIC STATES OF RADICAL CATIONS OF HEXAFLUOROBENZENE, PENTAFLUOROBENZENE, 1,2,3,4-TETRAFLUOROBENZENE, 1,2,3,5-TETRAFLUOROBENZENE, 1,2,4,5-TETRAFLUOROBENZENE, 1,3,5-TRIFLUOROBENZENE, 1,2,4-TRIFLUOROBENZENE AND 1,3-DIFLUOROBENZENE
ALLAN, M
MAIER, JP
MARTHALER, O
[J]. CHEMICAL PHYSICS, 1977, 26 (01) : 131 - 140
[2] EMISSION-SPECTRA OF RADICAL CATIONS OF HEXA-FLUOROBENZENES, PENTA-FLUOROBENZENES, TETRA-FLUOROBENZENES, AND TRI-FLUOROBENZENES
ALLAN, M
MAIER, JP
[J]. CHEMICAL PHYSICS LETTERS, 1975, 34 (03) : 442 - 446
[3] BEST AP, 1946, J CHEM SOC, P235
[4] LASER FLUORESCENCE-SPECTRA OF HEXAFLUOROBENZENE CATION IN SOLID ARGON
BONDYBEY, VE
ENGLISH, JH
MILLER, TA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (16) : 5251 - 5252
[5] LASER-INDUCED FLUORESCENCE FROM FLUOROBENZENE RADICAL CATIONS IN THE GAS-PHASE
BONDYBEY, VE
MILLER, TA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (01) : 138 - 146
[6] BONDYBEY VE, UNPUBLISHED
[7] COSSARTMAGOS C, UNPUBLISHED
[8] DAINTITH J, 1972, MOL SPECTROSC, P16
[9] FERGUSON EE, 1935, J CHEM PHYS, V21, P1470
[10] LASER FLUORESCENCE EXCITATION-SPECTRA OF 1,3,5-TRIFLUOROBENZENE RADICAL CATION
MILLER, TA
BONDYBEY, VE
[J]. CHEMICAL PHYSICS LETTERS, 1978, 58 (03) : 454 - 456

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