THE SYNTHESIS AND CRYSTAL-STRUCTURE OF 1,2,3-TRITHIA[3]OSMOCENOPHANE

被引：11

作者：

ABEL, EW

LONG, NJ

OSBORNE, AG

HURSTHOUSE, MB

MAZID, MA

机构：

[1] UNIV EXETER,DEPT CHEM,EXETER EX4 4RJ,DEVON,ENGLAND

[2] UNIV LONDON,QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)80102-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first bridged osmocene compound, 1,2,3-trithia[3]osmocenophane (1), has been prepared by the reaction of 1,1'-dilithioosmocene with elemental sulphur, and its crystal structure determined by X-ray diffraction methods. The S-S bond lengths are 2.039(9) and 2.055(9) angstrom and the S-S-S bond angle is 106.4(4)-degrees. The S-C bond lengths are 1.760(12) and 1.752(11) angstrom with S-S-C bond angles of 103.1(5) and 103.5(5)-degrees. The cyclopentadienyl rings are in an eclipsed conformation and are slightly inclined to each other, with a non-bonded S(l)-S(3) separation of 3.279 angstrom.

引用

页码：117 / 122

页数：6

共 26 条

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