FACTORS INFLUENCING LINKAGE ISOMERISM OF THE OXIMATO GROUP IN THE NI(II), CO(II) AND CU(II) COMPLEXES OF VICINAL OXIME-IMINE LIGANDS

被引：12

作者：

ALY, MM

STEPHANOS, JJ

机构：

[1] Chemistry Department, Faculty of Science, El-Menoufia University, Shebin El-Kom

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1993年 / 293卷

关键词：

D O I：

10.1016/0022-2860(93)80018-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

The vibrational energy of either N-0 or C=N groups in the chelate ring as well as C=O of LM (H2L=N,N'-ethylenebis(isonitrosoacetylacetoneimine), M=divalent Ni, Co Dr Cu) is related to the second ionization potential of the metal ion. This relationship is used for the calculation of the stretching vibration of either nu(N-0), nu(C=N) or nu(C=O) group. The contribution of any of these groups to the stability of the chelate isomers (five- or six-membered chelate ring) is discussed

引用

页码：75 / 76

页数：2

共 5 条

[1]

SIZE AND STABILITY OF CHELATE RINGS IN COORDINATION-COMPOUNDS OF COBALT(II), MANGANESE(II), IRON(III) AND PALLADIUM(II) WITH VICINAL OXIME-IMINE LIGANDS [J].