PHOTOLYSIS OF AMIBEN (3-AMINO-2,5-DICHLOROBENZOIC ACID) AND ITS METHYL ESTER

被引:8
作者
PLIMMER, JR
HUMMER, BE
机构
[1] Crops Research Division, Agricultural Research Service, U. S. Department of Agriculture, Beltsville
关键词
D O I
10.1021/jf60161a606
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
The products of irradiation of amiben (3-amino-2,5-dichlorobenzoic acid) and its methyl ester have been investigated. Under conditions in which oxidation is prevented these compounds undergo selective loss of the 2-chloro substituent to give 3-amino-5-chlorobenzoic acid and methyl 3-amino-5-chlorobenzoate, respectively. Irradiation of amiben in the presence of air or oxygen affords a complex mixture of oxidation products. © 1969, American Chemical Society. All rights reserved.
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页码:83 / &
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