STEREOCHEMISTRY OF MANNICH BASES .I. ABSOLUTE CONFIGURATION OF SOME ALPHA-METHYL-BETA-AMINO-KETONES

被引：8

作者：

ANGELONI, AS

GOTTAREL.G

TRAMONTI.M

机构：

[1] Istituto di Chimica degli Intermedi della Universita', Bologna

来源：

TETRAHEDRON | 1969年 / 25卷 / 18期

关键词：

D O I：

10.1016/S0040-4020(01)82949-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The absolute configuration of (+)-α-methyl-β-dimethylaminopropiophenone (Ia) was found to be S by chemical correlation with R(-)-α-methyl-β-alanine. The absolute configuration of (+)-α-methyl-β-piperidino- and of (-)-α-methyl-β-morpholinopropiophenone (Ib and Ic) was found to be S and R, respectively, by comparison of their ORD spectra with that of the keto-base (Ia). © 1969.

引用

页码：4147 / +

页数：1

共 11 条

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