RING-OPENING METATHESIS POLYMERIZATION OF 1,1-DIPHENYL-1-SILA-CYCLOPENT-3-ENE

被引：18

作者：

STONICH, DA ^{[1
]}

WEBER, WP ^{[1
]}

机构：

[1] UNIV SO CALIF,DP & KB LOKER HYDROCARBON RES INST,DEPT CHEM,LOS ANGELES,CA 90089

来源：

POLYMER BULLETIN | 1991年 / 25卷 / 06期

关键词：

D O I：

10.1007/BF01032657

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

1,1-Diphenyl-1-silacyclopent-3-ene (I) has been polymerized by ring opening metathesis using tungsten hexachloride and either cyclopentene or cyclohexene as an initiator, with or without tetraphenyltin as a cocatalyst. The product polymer poly(1,1-diphenyl-1-sila-ciis-pent-3-ene) (II) has been characterized by H-1, C-13, and Si-29 NMR and IR spectroscopy.

引用

页码：629 / 631

页数：3

共 12 条

[1] ON THE OXIDATION-STATE OF THE TUNGSTEN ATOM IN WCL6-BASED METATHESIS CATALYSTS USED FOR THE RING-OPENING POLYMERIZATION OF CYCLOOLEFINS [J].

CEAUSESCU, E ;

CORNILESCU, A ;

NICOLESCU, E ;

POPESCU, M ;

COCA, S ;

CUZMICI, M ;

OPRESCU, C ;

DIMONIE, M ;

TEODORESCU, M ;

HUBCA, GH ;

DRAGUTAN, V ;

CHIPARA, M ;

GROSESCU, R ;

VASILESCU, A .

JOURNAL OF MOLECULAR CATALYSIS, 1988, 46 (1-3) :405-413

[2] NEW ASPECTS OF THE MECHANISM OF THE RING-OPENING POLYMERIZATION OF CYCLO-OLEFINS. [J].

Ceausescu, E. ;

Cornilescu, A. ;

Nicolescu, E. ;

Popescu, M. ;

Coca, S. ;

Belloiu, C. ;

Dimonie, M. ;

Gherorghui, M. ;

Dragutan, V. ;

Chipara, M. .

Journal of molecular catalysis, 1983, 28 (1-3) :337-349

[3] NEW FORMATION OF SILICON-CARBON BONDS FROM CHLOROSILANES .6. DOUBLE SILYLATION OF 1,4-CONJUGATED DIENES [J].

DUNOGUES, J ;

CALAS, R ;

DEDIER, J ;

PISCIOTT.F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1970, 25 (01) :51-&

[4]

FINKELSHTEIN ES, 1981, IAN SSSR KH, V3, P641

[5] PROTON-DECOUPLED NMR-SPECTRA OF C-13 WITH NUCLEAR OVERHAUSER EFFECT SUPPRESSED [J].

FREEMAN, R ;

KAPTEIN, R ;

HILL, HDW .

JOURNAL OF MAGNETIC RESONANCE, 1972, 7 (03) :327-&

[6] RING-OPENING POLYMERIZATIONS OF CYCLIC OLEFINS [J].

HEIN, PR .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1973, 11 (01) :163-173

[7]

IVIN KJ, 1983, OLEFIN METATHESIS, P227

[8] RING OPENING POLYMERIZATION OF 1,1-DIMETHYL-1-SILACYCLO-3-PENTENE [J].

LAMMENS, H ;

SARTORI, G ;

SIFFERT, J ;

SPRECHER, N .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER LETTERS, 1971, 9 (05) :341-&

[9]

MANUEL GRB, 1974, SYNTHE REACT INORG M, V77, P2745

[10]

PARK YT, 1989, POLYM B, V522, P349

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