SYNTHESIS OF THE 5-COORDINATE ORGANOPLATINUM CATION [PTME(PP3)]+ (PP3 = P(CH2CH2PPH2)3) BY OXIDATIVE ADDITION OF METHYL-IODIDE TO [PT2(MU-PP3)2]

被引：4

作者：

PETER, M

PROBST, M

PERINGER, P

MULLER, EP

机构：

[1] UNIV INNSBRUCK,INST ANORGAN & ANALYT CHEM,INNRAIN 52A,A-6020 INNSBRUCK,AUSTRIA

[2] UNIV INNSBRUCK,INST ORGAN & PHARMAZEUT CHEM,A-6020 INNSBRUCK,AUSTRIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80015-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Pt2(mu-pp3)2] (pp3 =P(CH2CH2PPh2)3), produced by treatment of [PtH(pp3)]+ with sodium amalgam, has been shown to react with methyl iodide to give [PtMe(pp3)]+. The new complexes have been characterized by H-1, P-31 and Pt-195 NMR spectroscopy.

引用

页码：C29 / C32

页数：4

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