AN EFFICIENT PHOSPHORYLATION METHOD USING A NEW PHOSPHITYLATING AGENT, 2-DIETHYLAMINO-1,3,2-BENZODIOXAPHOSPHEPANE

被引：107

作者：

WATANABE, Y

KOMODA, Y

EBISUYA, K

OZAKI, S

机构：

[1] Department of Resources Chemistry, Faculty of Engineering, F. Ehime University. Matsuyama

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)94385-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of alcohols containing polyols like inositol derivatives were efficiently phosphitylated by the reaction with 2-diethylamino-1,3,2-benzodioxaphosphepane in the presence of tetrazole and the resulting phosphites were oxidized with m CPBA or sulfur to yield the corresponding phosphates or thiophosphatea in excellent yields. © 1990.

引用

页码：255 / 256

页数：2

共 21 条

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