DECOMPOSITION RATE OF CHEMICALLY ACTIVATED METHYLAMINE

被引：9

作者：

CHAO, KJ

LIN, CL

HSU, M

HO, SY

机构：

[1] Department of Chemistry, National Tsing Hua University, Hsinchu

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1979年 / 83卷 / 10期

关键词：

D O I：

10.1021/j100473a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A study of the decomposition of the activated methylamine formed by methylene radical reacting with ammonia is presented. Singlet methylene radicals were produced by diazomethane photolysis at 4358 and 3660 A in the presence of added oxygen. The measured decomposition rates are 1.7 × 1010 and 2.3 × 1010 s-1 in the 4358- and 3660-Å systems, respectively. The result is consistent with RRKM calculations. © 1979 American Chemical Society.

引用

页码：1241 / 1243

页数：3

共 14 条

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