MOLECULAR DESIGN OF CROWN ETHERS .7. SYNTHESES AND CATION SELECTIVITIES OF UNSUBSTITUTED 12-CROWN-4 TO 16-CROWN-4

被引：36

作者：

LIU, Y

INOUE, Y

HAKUSHI, T

机构：

[1] HIMEJI INST TECHNOL, FAC SCI, DEPT AGRON & SOIL SCI, HIMEJI, HYOGO 67122, JAPAN

[2] ACAD SINICA, LANZHOU INST CHEM PHYS, LANZHOU, PEOPLES R CHINA

[3] HIMEJI INST TECHNOL, FAC ENGN, DEPT APPL CHEM, HIMEJI, HYOGO 67122, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 10期

关键词：

D O I：

10.1246/bcsj.63.3044

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvent extraction of aqueous alkali and some heavy metal picrates with the title compounds showed that, with most cations except for Li+, Na+, and Ag+, the extractability decreases monotonically as the ring size increases from 12 to 16. However, 14-crown-4 showed the highest extractability and selectivity for Li+ over the larger alkali metals, while 15-crown-4 exhibited the highest Ag+/Tl+ selectivity. © 1990 The Chemical Society of Japan.

引用

收藏

页码：3044 / 3046

页数：3

相关论文

共 28 条

[1] 1,5,9,13-TETRAOXACYCLOHEXADECANE AND ITS 3,3,7,7,11,11,15,15-OCTAMETHYL DERIVATIVE AS NEUTRAL CARRIERS FOR LITHIUM ION THROUGH ARTIFICIAL MEMBRANES [J].

AALMO, KM ;

KRANE, J .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1982, 36 (03) :227-234

[2] SOME TETRAOXACYCLOTETRADECANES AND TETRAOXACYCLOHEXADECANES [J].

BORGEN, G ;

DALE, J ;

TEIEN, G .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1979, 33 (01) :15-21

[3] STEREOCHEMISTRY OF CROWN ETHERS AND THEIR COMPLEXES IN THE SOLID-STATE - C-13 CPMAS NMR AND X-RAY CRYSTALLOGRAPHIC STUDIES OF CONFIGURATIONALLY ISOMERIC DICYCLOHEXANO-14-CROWN-4 ETHERS, DIBENZO-14-CROWN-4 ETHER, AND SOME LITHIUM THIOCYANATE SALTS [J].

BUCHANAN, GW ;

KIRBY, RA ;

CHARLAND, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (08) :2477-2483

[4] MACROBICYCLIC POLYETHERS WITH BRIDGEHEAD CARBON-ATOMS [J].

COXON, AC ;

STODDART, JF .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (07) :767-785

[5] FUNCTIONALIZED 13-CROWN-4, 14-CROWN-4, 15-CROWN-4, AND 16-CROWN-4 COMPOUNDS - SYNTHESIS AND LITHIUM ION COMPLEXATION [J].

CZECH, BP ;

BABB, DA ;

SON, B ;

BARTSCH, RA .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (25) :4805-4810

[6] ON THE CRYSTAL-STRUCTURE OF THE (1-1) COMPLEX BETWEEN LITHIUM THIOCYANATE AND 1,4,7,10-TETRAOXACYCLODODECANE AT ROOM-TEMPERATURE [J].

GROTH, P .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1981, 35 (06) :463-465

[7]

HU J, UNPUB

[8] MOLECULAR DESIGN OF CROWN ETHERS .5. 14,16-BRIDGED 16-CROWN-5 - DRASTIC ENHANCEMENT IN CATION-BINDING ABILITY [J].

INOUE, Y ;

WADA, K ;

OUCHI, M ;

TAI, A ;

HAKUSHI, T .

CHEMISTRY LETTERS, 1988, (06) :1005-1008

[9] MOLECULAR DESIGN OF CROWN ETHERS .3. EXTRACTION OF ALKALINE-EARTH AND HEAVY-METAL PICRATES WITH 14-CROWN-5 TO 17-CROWN-5 AND 17-CROWN-6 TO 22-CROWN-6 [J].

INOUE, Y ;

OUCHI, M ;

HAKUSHI, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (02) :525-530

[10] MOLECULAR DESIGN OF CROWN ETHERS .6. SUBSTITUTION EFFECT IN 16-CROWN-5 [J].

INOUE, Y ;

WADA, K ;

LIU, Y ;

OUCHI, M ;

TAI, A ;

HAKUSHI, T .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (22) :5268-5272