STEREOCHEMISTRY IN THE REDUCTION OF THE C=C BOND OF VERBENONE WITH A REDUCTASE FROM THE CULTURED-CELLS OF NICOTIANA-TABACUM

被引：14

作者：

HIRATA, T

IZUMI, S

SHIMODA, K

HAYASHI, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 18期

关键词：

D O I：

10.1039/c39930001426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of the C=C bond of verbenone by a reductase from the cultured cells of Nicotiana tabacum involves syn-addition of the hydrogen atom to the re-re face of the double bond; the hydrogen atoms participating in the reduction at C-2 and C-3 of verbenone originate from the pro-4S hydrogen of NADPH and the medium, respectively.

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页码：1426 / 1427

页数：2

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