CONTROLLING STEREOCHEMISTRY IN C-C AND C-H BOND FORMATION WITH ELECTRONICALLY ASYMMETRIC ORGANOMETALLICS AND CHIRAL POISONS

被引：74

作者：

FALLER, JW

MAZZIERI, MR

NGUYEN, JT

PARR, J

TOKUNAGA, M

机构：

[1] Department of Chemistry, Yale University, New Haven, Connecticut

来源：

PURE AND APPLIED CHEMISTRY | 1994年 / 66卷 / 07期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1351/pac199466071463

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Air stable (cyclopentadienyl)Mo(NO)(halide)(eta3-allyl) complexes add to aldehydes to yield homoallylic alcohols in high enantioselectivity and diastereoselectivity. A new strategy, chiral poisoning, is applied to asymmetric hydrogenation and the kinetic resolution of allylic alcohols using transition metal catalysts prepared from racemic bis-phosphine ligands.

引用

页码：1463 / 1469

页数：7

共 36 条

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