SYNDIOSPECIFIC POLYMERIZATION OF STYRENE WITH ARENE TITANIUM(II) COMPLEXES AS CATALYST PRECURSORS

被引：32

作者：

KAMINSKY, W

PARK, YW

机构：

[1] Institut für Technische und Makromolekulare Chemie, Universität Hamburg, Hamburg, D-20146

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1995年 / 16卷 / 05期

关键词：

D O I：

10.1002/marc.1995.030160501

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The divalent titanium compounds [(eta(6)-C(6)H(5)Me)Ti(Cl2AlCl2)(2)] (1) and [(eta(6)-C(6)Me(6))Ti(Cl2AlCl2)(2)] (2) are syndiospecific catalysts in the polymerization of styrene when activated with methylaluminoxane. The polystyrene is of exceptionally high molecular weight.

引用

页码：343 / 346

页数：4

共 20 条

[1]

BAEKELMANS P, 1975, Patent No. 2621874

[2]

CANDLIN JP, 1977, Patent No. 2822542

[3] SYNDIOSPECIFIC POLYMERIZATION OF STYRENE .2. MONOCYCLOPENTADIENYLTRIBUTOXY TITANIUM METHYLALUMINOXANE CATALYST [J].