CATION-RADICALS - TRIS-(PARA-BROMOPHENYL)AMMINIUM PERCHLORATE AND HEXACHLOROANTIMONATE

被引:261
作者
BELL, FA
LEDWITH, A
SHERRINGTON, DC
机构
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 19期
关键词
D O I
10.1039/j39690002719
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Stable triarylamminium salts may be used as convenient one-electron oxidants for a range of organic molecules. Synthesis and characterisation of perchlorate and hexachloroantimonate salts of the tris- (p-bromophenyl)amminium cation [(p-BrC6H4)3N+] are described in detail. The hexachloroantimonate is easier to prepare and is much the more stable, both thermally and photochemically.
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页码:2719 / +
页数:1
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