ELECTROCHEMICAL POLYMERIZATION OF 4-METHYL-4'-VINYL-2,2'-BIPYRIDINE-CONTAINING METAL-COMPLEXES - POLYMER STRUCTURE AND MECHANISM OF FORMATION

被引：37

作者：

ELLIOTT, CM ^{[1
]}

BALDY, CJ ^{[1
]}

NUWAYSIR, LM ^{[1
]}

WILKINS, CL ^{[1
]}

机构：

[1] UNIV CALIF RIVERSIDE,RIVERSIDE,CA 92521

来源：

INORGANIC CHEMISTRY | 1990年 / 29卷 / 03期

关键词：

D O I：

10.1021/ic00328a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polymer structure and mechanism of formation of electroreductively polymerized 4-methyl-4′-vinyl-2,2′-bipyridine-containing metal complexes are described. Results from TLC and laser desorption Fourier transform mass spectrometry demonstrate that normal “polyvinyl-type” chains are formed through chain propagation. For electrochemically polymerized poly-Fe(vbpy)32+an average chain length of seven repeat monomer units is determined. Separate copolymerization studies of mono- and tris(vinyl)-substituted complexes provide additional information on the nature of the polymerization process. © 1990, American Chemical Society. All rights reserved.

引用

页码：389 / 392

页数：4

共 19 条

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