REACTION OF 1-BROMO-1,2-DIENES WITH ALKYLCUPRATES AS A REGIOSELECTIVE AND STEREOSELECTIVE ROUTE TO ACETYLENIC OR ALLENIC COMPOUNDS

被引：13

作者：

POLIZZI, C ^{[1
]}

CONSOLONI, C ^{[1
]}

LARDICCI, L ^{[1
]}

CAPORUSSO, AM ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO CHIM & CHIM IND,CNR,I-56100 PISA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 417卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)80179-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alkylcuprates react with 1-bromo-1,2-dienes to give allenic and/or acetylenic products. The selectivity of the crosscoupling is markedly dependent on the nature of the copper reagent, which plays a prominent role in determining both the regio- and the stereo-chemistry. The preparative aspects of these copper-induced reactions are discussed and their possible mechanism discussed.

引用

页码：289 / 304

页数：16

共 41 条

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