CONDUCTING POLYMER-CLAY COMPOSITES FOR ELECTROCHEMICAL APPLICATIONS

被引：16

作者：

FAGUY, PW ^{[1
]}

MA, WL ^{[1
]}

LOWE, JA ^{[1
]}

PAN, WP ^{[1
]}

BROWN, T ^{[1
]}

机构：

[1] WESTERN KENTUCKY UNIV,DEPT CHEM,BOWLING GREEN,KY 42101

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1994年 / 4卷 / 05期

关键词：

D O I：

10.1039/jm9940400771

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pyrrole can be polymerized within montmorillonite clays via chemical means utilizing Fe3+ and Cu2+ as the oxidizing species. The resultant composite has properties of both the conducting polymer and the host material. Vibrational spectroscopy, thermal analysis and conductivity data all indicate that polypyrrole is present in the interlayer region of the clays utilized. Electrochemically, the conducting polymer-clay composite shows promise for both sensor and electrolysis applications.

引用

页码：771 / 772

页数：2

共 9 条

[1] CLAY MODIFIED ELECTRODES .8. ELECTROCHEMICAL-BEHAVIOR AT MONTMORILLONITE AND POLYPYRROLE MONTMORILLONITE FILMS ON PLATINUM AND GLASSY-CARBON ELECTRODES [J].

CASTROACUNA, CM ;

FAN, FRF ;

BARD, AJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1987, 234 (1-2) :347-353

[2] ADSORPTION OF PYRROLE ON FE(II)Y, FE(III)Y, CU(I)Y, AND CU(II)Y ZEOLITES [J].

CHAO, TH ;

ERF, HA .

JOURNAL OF CATALYSIS, 1986, 100 (02) :492-499

[3]

DIAZ AF, 1986, HDB CONDUCTING POLYM, V1, P81

[4] POLYTHIOPHENES AND OLIGOTHIOPHENES IN ZEOLITE HOSTS - CONJUGATED NANOMETER-SIZE FILAMENTS [J].

ENZEL, P ;

BEIN, T .

SYNTHETIC METALS, 1993, 55 (2-3) :1238-1245

[5]

FAGUY PW, UNPUB ELECTROCHIM AC

[6]

KANATZIDIS MG, 1989, J AM CHEM SOC, V111, P4138

[7] METAL-INSULATOR MOLECULAR MULTILAYERS OF ELECTROACTIVE POLYMERS - INTERCALATION OF POLYANILINE IN MICA-TYPE LAYERED SILICATES [J].

MEHROTRA, V ;

GIANNELIS, EP .

SOLID STATE COMMUNICATIONS, 1991, 77 (02) :155-158

[8] ANALYTICAL IMPLICATIONS OF ZEOLITES IN OVERLAYERS AT ELECTRODES [J].

ROLISON, DR ;

NOWAK, RJ ;

WELSH, TA ;

MURRAY, CG .

TALANTA, 1991, 38 (01) :27-35

[9] ELECTRICALLY CONDUCTING POLYMERS - A REVIEW OF THE ELECTROPOLYMERIZATION REACTION, OF THE EFFECTS OF CHEMICAL-STRUCTURE ON POLYMER FILM PROPERTIES, AND OF APPLICATIONS TOWARDS TECHNOLOGY [J].

WALTMAN, RJ ;

BARGON, J .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1986, 64 (01) :76-95

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