THE SYNTHESIS AND STRUCTURE OF ([PIM(PRI,BUT)]ZNOH)(CLO4) - A TRIS(IMIDAZOLYL)PHOSPHINE ZINC HYDROXIDE COMPLEX AND A PROPOSED STRUCTURAL MODEL FOR CARBONIC-ANHYDRASE

被引：83

作者：

KIMBLIN, C

ALLEN, WE

PARKIN, G

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

[2] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001813

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The zinc hydroxide complex {[Pim(Pri,But)]ZnOH}(ClO4) is synthesized by the reaction of [Pim(Pri,But)] with Zn(ClO4)(2) . 6H(2)O; {[Pim(Pri,But)]ZnOH}(ClO4) is the first structurally characterized monomeric zinc hydroxide complex supported by imidazole functionalities and is therefore an excellent structural model for the active site of carbonic anhydrase.

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页码：1813 / 1815

页数：3

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