CHEMISTRY OF TRIVALENT URANIUM - SYNTHESIS AND REACTION CHEMISTRY OF THE TETRAHYDROFURAN ADDUCT OF URANIUM TRICHLORIDE, UCL3(THF)X

被引：53

作者：

MOODY, DC ^{[1
]}

ODOM, JD ^{[1
]}

机构：

[1] UNIV S CAROLINA,DEPT CHEM,COLUMBIA,SC 29208

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1979年 / 41卷 / 04期

关键词：

D O I：

10.1016/0022-1902(79)80439-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Uranium tetrachloride in THF solution has been found to react with NaH to yield UCl3(THF)x. From this solution the 1:1 adduct UCl3(THF) has been isolated. Unlike the parent UCl3, this material is soluble in THF enabling the study of a variety of reactions. The reactions of UCl3(THF)x with 4-picoline-N-oxide, TICp, NaCp and NaBH4 have been studied as well as the decomposition of UCl3(THF) at elevated temperatures. © 1979.

引用

页码：533 / 535

页数：3

共 15 条

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