NMR SPIN-LATTICE RELAXATION STUDIES OF METHYL ISOCYANIDE IN SOLUTION

被引：12

作者：

DECATUR, JD ^{[1
]}

FARRAR, TC ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MADISON,WI 53706

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 19期

关键词：

D O I：

10.1021/j100382a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The nitrogen quadrupole coupling constant, χN, in methyl isocyanide has been measured in solution by NMR spin-lattice (T1) relaxation measurements. The value of χN, 67 kHz, is the smallest yet measured and is the result of solvent-solute interactions. Rotating frame spin-lattice relaxation times, T1ρ, for nitrogen were also measured. They are in agreement with the spin-lattice relaxation time results. © 1990 American Chemical Society.

引用

页码：7391 / 7394

页数：4

共 18 条

[1]

ABRAGAM A, 1961, PRINCIPLES NUCLEAR M, pCH8

[2] ANOMALOUS N-14 QUADRUPOLE COUPLING-CONSTANT OF METHYL ISOCYANIDE IN LIQUID-CRYSTALS [J].