SYNTHESIS, STRUCTURE, AND GAS-PHASE DECOMPOSITION OF [CD(SC6H2TBU3)2]2 [CD(SEC6H2TBU3)2]2 - 1ST EXAMPLES OF LOW-COORDINATE VOLATILE CADMIUM CHALCOGENOLATO COMPLEXES

被引：144

作者：

BOCHMANN, M ^{[1
]}

WEBB, K ^{[1
]}

HARMAN, M ^{[1
]}

HURSTHOUSE, MB ^{[1
]}

机构：

[1] QUEEN MARY & WESTFIELD COLL,DEPT CHEM,LONDON E1 4NS,ENGLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 06期

关键词：

D O I：

10.1002/anie.199006381

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Volatile chalcogenolato complexes of cadmium with stertically demanding thio‐ and selenophenolato ligands can easily be prepared. In the solid state, the complexes 1 are dimeric with trigonal‐planar coordinated cadmium, whereas in solution they dissociate to monomers. They sublime at high temperatures and can be used as starting substances for the deposition of CdS and CdSe films respectively from the gas phase. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：638 / 639

页数：2

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