KINETIC RESOLUTIONS IN ANTIALDOL REACTIONS - ASYMMETRIC-SYNTHESIS OF HETEROCYCLES WITH PHENYLTHIO MIGRATION

被引：1

作者：

CHIBALE, K

WARREN, S

机构：

[1] University Chemical Laboratories, Lensfield Road, Cambridge

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1993年 / 74卷 / 1-4期

关键词：

D O I：

10.1080/10426509308038135

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Kinetic resolutions in Lewis acid catalysed asymmetric anti aldol reactions of the boron enolate of imide (2) with racemic 2-phenylthio aldehydes (3) give good Yields of Felkin anti,anti aldols (6). The synthesis of homochiral cyclic ethers (4) and a simple novel route to homochiral lactones (5) are described.

引用

页码：401 / 402

页数：2