ASYMMETRIC HYDROGENATION IN WATER BY A RHODIUM COMPLEX OF SULFONATED 2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL (BINAP)

被引：56

作者：

WAN, KT ^{[1
]}

DAVIS, ME ^{[1
]}

机构：

[1] CALTECH,DIV CHEM & CHEM ENGN,PASADENA,CA 91125

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 16期

关键词：

D O I：

10.1039/c39930001262

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of sulfonated 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl (binap) is reported; a rhodium complex of this ligand is the first to perform asymmetric hydrogenation in neat water with optical yields as high as those obtained in nonaqueous solvent.

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页码：1262 / 1264

页数：3

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