HYDROCARBON METAL SULPHIDE COMPLEXES .V. COMPARISONS BETWEEN REACTIVITY OF CYCLOPENTA-, -HEXA-, AND -HEPTADIENYLIRON COMPLEXES

被引:8
作者
KNOX, GR
PRYDE, A
机构
[1] Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow
关键词
D O I
10.1016/S0022-328X(00)80245-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Stabilisation of iron carbonyl sulphide complexes by homocyclic dienyl ligands increases in the order cyclopentadienyl > cycloheptadienyl ≫ cyclohexadienyl. Nucleophilic attack of sulphide ion occurs at the cycloalkadienyl ligand in the corresponding cationic tricarbonyliron derivatives. © 1969.
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页码:169 / &
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