TRIMAGNESIUM RHENIUM(I) HEPTAHYDRIDE, MG3REH7, CONTAINING OCTAHEDRAL [REH6]5- COMPLEX ANIONS

被引：19

作者：

HUANG, B

YVON, K

FISCHER, P

机构：

[1] UNIV GENEVA,CRISTALLOG LAB,24 QUAI E ANSERMET,CH-1211 GENEVA,SWITZERLAND

[2] ETH ZURICH,NEUTRONENSTREUUNG LAB,CH-5232 VILLIGEN,SWITZERLAND

[3] PAUL SCHERRER INST,CH-5232 VILLIGEN,SWITZERLAND

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 1993年 / 197卷 / 01期

关键词：

D O I：

10.1016/0925-8388(93)90625-W

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mg3ReH7 and its deuteride were synthesized by the reaction of magnesium and rhenium powders at 510-520-degrees-C and 120-155 bar hydrogen (deuterium) pressure and characterized by X-ray and neutron powder diffraction. They crystallize with hexagonal symmetry (space group P6(3)/mmc (No. 194); hydride: a = 4.8615(2) angstrom, c = 10.5937(5) angstrom; deuteride: a = 4.8539(2) angstrom, c = 10.5699(7) angstrom). The structure contains a nearly regular octahedral 18-electron [ReD6]5- complex anion with bond distances [Re-6D1] = 1.724(4) angstrom and a D - anion coordinated by five magnesium atoms in a trigonal bipyramidal configuration with bond distances [D2-2Mg1] = 1.901(4) angstrom and [D2-3Mg2] = 2.8024(1) angstrom.

引用

页码：97 / 99

页数：3

共 13 条

[1] TRANSITION METAL-HYDROGEN COMPOUNDS .2. CRYSTAL + MOLECULAR STRUCTURE OF POTASSIUM RHENIUM HYDRIDE K2REH9
ABRAHAMS, SC
KNOX, K
GINSBERG, AP
[J]. INORGANIC CHEMISTRY, 1964, 3 (04) : 558 - &
[2] NA3RHH6, NA3IRH6 AND LI3IRH6, NEW COMPLEX HYDRIDES WITH ISOLATED [RHH6](3-)-OCTAHEDRA AND [IRH6](3-)-OCTAHEDRA
BRONGER, W
GEHLEN, M
AUFFERMANN, G
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1991, 176 (02) : 255 - 262
[3] DIMAGNESIUM IRON(II) HYDRIDE, MG2FEH6, CONTAINING OCTAHEDRAL FEH64- ANIONS
DIDISHEIM, JJ
ZOLLIKER, P
YVON, K
FISCHER, P
SCHEFER, J
GUBELMANN, M
WILLIAMS, AF
[J]. INORGANIC CHEMISTRY, 1984, 23 (13) : 1953 - 1957
[4] STRONTIUM DIMAGNESIUM IRON OCTAHYDRIDE, SRMG2FEH8, CONTAINING OCTAHEDRAL [FEH6]4- COMPLEX ANIONS
HUANG, B
YVON, K
FISCHER, P
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 187 (01) : 227 - 232
[5] AN AUTOMATED LOW-TEMPERATURE GUINIER X-RAY DIFFRACTOMETER AND CAMERA
IHRINGER, J
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1982, 15 (FEB) : 1 - 4
[6] AN AUTOMATIC MICRO-DENSITOMETER FOR X-RAY-POWDER DIFFRACTION PHOTOGRAPHS
JOHANSSON, KE
PALM, T
WERNER, PE
[J]. JOURNAL OF PHYSICS E-SCIENTIFIC INSTRUMENTS, 1980, 13 (12): : 1289 - 1291
[7] X-RAY DETERMINATION OF CRYSTAL STRUCTURE OF POTASSIUM RHENIUM HYDRIDE
KNOX, K
GINSBERG, AP
[J]. INORGANIC CHEMISTRY, 1964, 3 (04) : 555 - &
[8] MG2OSH6 - A NEW TERNARY HYDRIDE WITH THE K2PTCL6-TYPE STRUCTURE
KRITIKOS, M
NOREUS, D
BOGDANOVIC, B
WILCZOK, U
[J]. JOURNAL OF THE LESS-COMMON METALS, 1990, 161 (02): : 337 - 340
[9] TERNARY HYDRIDES OF CALCIUM AND STRONTIUM WITH IRIDIUM, RHODIUM AND RUTHENIUM
MOYER, RO
STANITSKI, C
TANAKA, J
KAY, MI
KLEINBERG, R
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1971, 3 (04) : 541 - +
[10] SAKTHIVEL A, 1990, PROGRAM DBWS9006 DBW

← 1 2 →