(P-ANISALDEHYDE THIOSEMICARBAZONATO)DIMETHYLTHALLIUM(III) - AN UNUSUAL STRUCTURE FOR A COORDINATED THIOSEMICARBAZONE

被引：35

作者：

CASAS, JS

CASTELLANO, EE

MACIAS, A

RODRIGUEZARGUELLES, MC

SANCHEZ, A

SORDO, J

机构：

[1] UNIV SAO PAULO, INST FIS & QUIM SAO CARLOS, BR-13560 SAO CARLOS, BRAZIL

[2] UNIV VIGO, DEPT QUIM PURA & APL, E-36200 VIGO, SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 02期

关键词：

D O I：

10.1039/dt9930000353

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of an ethanolic solution of p-anisaldehyde thiosemicarbazone (HL) with an aqueous [TlMe2(OH)] solution afforded the compound [TlMe2L] in which the deprotonated thiosemicarbazone retains the typical structure of free thiosemicarbazones, an unusual arrangement of this type of ligand in a metallic complex.

引用

收藏

页码：353 / 354

页数：2

相关论文

共 17 条

[1] SOME HETEROCYCLIC THIOSEMICARBAZONES [J].

ANDERSON, FE ;

DUCA, CJ ;

SCUDI, JV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (10) :4967-4968

[2] VAN DER WAALS VOLUMES + RADII [J].

BONDI, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) :441-+

[3] TL-205 SPIN-LATTICE RELAXATION IN DIALKYLTHALLIUM(III) DERIVATIVES - IMPORTANCE OF CHEMICAL-SHIFT ANISOTROPY RELAXATION AND EFFECTS ON NMR-SPECTRA OF COUPLED NUCLEI [J].

BRADY, F ;

MATTHEWS, RW ;

FORSTER, MJ ;

GILLIES, DG .

INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1981, 17 (5-6) :155-159

[4] TRANSITION-METAL COMPLEXES OF THIOSEMICARBAZIDE AND THIOSEMICARBAZONES [J].

CAMPBELL, MJM .

COORDINATION CHEMISTRY REVIEWS, 1975, 15 (2-3) :279-319

[5]

CASAS J, UNPUB

[6] COMPARATIVE STRUCTURAL STUDY OF DIMETHYL(PYRIDINE-2-THIOLATO)THALLIUM(III) AND DIMETHYLBIS(PYRIDINE-2-THIOLATO)TIN(IV) [J].

CASTANO, MV ;

MACIAS, A ;

CASTINEIRAS, A ;

GONZALEZ, AS ;

MARTINEZ, EG ;

CASAS, JS ;

SORDO, J ;

HILLER, W ;

CASTELLANO, EE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (03) :1001-1005

[7] CRYSTAL AND MOLECULAR-STRUCTURES OF (1)ACETATO-BIS(ACETONE S-METHYLTHIOSEMICARBAZONE)COBALT(II) IODIDE AND (2)ACETATO-BIS(ACETONE S-METHYLTHIOSEMICARBAZONE) NICKEL(II) IODIDE [J].

DIVJAKOVIC, V ;

RIBAR, B ;

LEOVAC, VM ;

GERBELEU, NV .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1981, 154 (1-2) :83-94

[8]

GERBELEU NV, 1977, RUSS J INORG CHEM, V22, P1009

[9] RELATIVE REACTIVITIES OF ORGANOMETALLIC COMPOUNDS .51. TRIMETHYLTHALLIUM [J].

GILMAN, H ;

JONES, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (03) :517-520

[10] SYNTHETIC, SPECTROSCOPIC, AND X-RAY STUDIES ON METHYLMERCURY(II) AND DIMETHYLTHALLIUM(III) COMPLEXES WITH CYCLOPENTANONE THIOSEMICARBAZONE [J].

MACIAS, A ;

RODRIGUEZARGUELLES, MC ;

SUAREZ, MI ;

SANCHEZ, A ;

CASAS, JS ;

SORDO, J ;

ENGLERT, U .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (09) :1787-1791