ORGANIC SYNTHESES BY MEANS OF NOBLE METAL COMPOUNDS .40. PALLADIUM-CATALYSED CARBONYLATION OF ALLYLIC ETHERS

被引：12

作者：

IMAMURA, S

TSUJI, J

机构：

[1] Basic Research Laboratories, Toyo Rayon Co., Ltd. Kamakura

来源：

TETRAHEDRON | 1969年 / 25卷 / 18期

关键词：

D O I：

10.1016/S0040-4020(01)82955-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium catalysed carbonylation of allylic ethers, especially 1,4-diethoxy-2-butene has been carried out. Hexenedioate, 5-ethoxy-3-pentenoate, 2-ethoxymethyl-3-butenoate, 3-pentenoate, pentadienoate were obtained and the mechanism of the allylic carbonylation and competing reactions are discussed. © 1969.

引用

页码：4187 / &

共 11 条

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[6] Robinson S. D., 1963, J CHEM SOC, P4806
[7] EINE REAKTION VON PALLADIUMCHLORID MIT ALLYLALKOHOL
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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1959, 71 (08) : 284 - 284
[8] ORGANIC SYNTHESES BY MEANS OF NOBLE METAL COMPOUNDS .28. SYNTHESES OF A NEW TYPE OF PI-ALLYLIC PALLADIUM COMPLEXES FROM ALPHA,BETA- AND BETA,GAMMA-UNSATURATED ESTERS AND THEIR CARBONYLATION
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[9] TSUJI J, 1963, TETRAHEDRON LETT, P1811
[10] TSUJI J, 1964, J AM CHEM SOC, V86, P4359

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