CRYSTALLOGRAPHIC APPROACH TO THE ORIGIN OF SYN-EFFECT

被引：11

作者：

INOMATA, K ^{[1
]}

HIRATA, T ^{[1
]}

SASADA, Y ^{[1
]}

ASADA, T ^{[1
]}

SENDA, H ^{[1
]}

KINOSHITA, H ^{[1
]}

机构：

[1] KANAZAWA UNIV, COLL LIBERAL ARTS, DEPT CHEM, KANAZAWA, ISHIKAWA 920, JAPAN

来源：

CHEMISTRY LETTERS | 1990年 / 12期

关键词：

D O I：

10.1246/cl.1990.2153

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was revealed by X-ray crystallography that alpha-unsubstituted (E)-vinyl sulfones have syn-conformation which seems to be the cause of ''syn-effect'' found in the conversion of (E)-vinyl sulfones to the corresponding allyl sulfones with a base under mild conditions. Syn-conformation of a thermal olefin in solid state was also confirmed.

引用

页码：2153 / 2156

页数：4

共 9 条

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