ELECTROCHEMICAL OXIDATION OF 1,2-DIMETHOXYBENZENE - SYNTHETIC ASPECTS

被引：16

作者：

MARQUEZ, OP

MARQUEZ, J

ORTIZ, R

机构：

[1] Laboratoru of Electrochemistry, Department of Chemistry, Universidad de Los Andes

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1993年 / 140卷 / 08期

关键词：

D O I：

10.1149/1.2220790

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Growth of a highly colored insoluble material on a platinum electrode by the oxidative reaction of 1,2-dimethoxybenzene (veratrole) in acetonitrile is observed when tetrabutylammonium tetrafluoroborate is used as supporting electrolyte. The organic yield of the deposit reaches 98% when short-timed electrolyses are performed. The main product has been characterized by several electrochemical and spectroscopic methods.

引用

页码：2163 / 2166

页数：4

共 25 条

[1] AMMAR F, 1973, J ELECTROANAL CHEM, V47, P146
[2] ANDERSON GM, 1979, J AM CHEM SOC, V101
[3] ELECTRODIMERIZATION .1. ONE-ELECTRON IRREVERSIBLE DIMERIZATION - DIAGNOSTIC CRITERIA AND RATE DETERMINATION PROCEDURES FOR VOLTAMMETRIC STUDIES
ANDRIEUX, CP
NADJO, L
SAVEANT, JM
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1970, 26 (01): : 147 - &
[4] BASCHE T, 1988, CHEM PHYS LETT, V114, P226
[5] MONOCATIONS, DICATIONS, AND TRICATIONS OF HEXAMETHOXYTRIPHENYLENE - NOVEL ANODIC TRIMERIZATION
BECHGAAR.K
PARKER, VD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (13) : 4749 - +
[6] BLOOR D, 1989, COMPREHENSIVE POLYM
[7] STUDIES ON KOLBE ELECTROLYTIC SYNTHESIS .6. ON MECHANISM OF ANODIC ACETOXYLATION
EBERSON, L
NYBERG, K
[J]. ACTA CHEMICA SCANDINAVICA, 1964, 18 (06): : 1568 - &
[8] REINVESTIGATION OF METHYL AND METHOXY GROUP HINDERED ROTATIONS IN P-DIMETHOXYBENZENE, BY COMPARISON OF DIELECTRIC AND FAR INFRARED-SPECTRA WITH C-13 NMR RELAXATION DATA
GOULON, J
CANET, D
EVANS, M
DAVIES, GJ
[J]. MOLECULAR PHYSICS, 1975, 30 (04) : 973 - 995
[9] A RAMAN-SPECTROSCOPIC STUDY OF THE LOW-FREQUENCY VIBRATIONS OF ORTHO-DIMETHOXYBENZENE AND ITS METHYL DEUTERATED ANALOGS
KONSCHIN, H
TYLLI, H
WESTERMARK, B
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1983, 102 (3-4) : 279 - 287
[10] KONSCHIN H, 1988, J MOL STRUC-THEOCHEM, V168, P293

← 1 2 3 →