SYNTHESES AND STRUCTURES OF 3 MONONUCLEAR COORDINATION-COMPOUNDS CONTAINING 6-COORDINATED AND 7-COORDINATED MANGANESE(II) IONS

被引：22

作者：

ANDRUH, M ^{[1
]}

HUBNER, K ^{[1
]}

NOLTEMEYER, M ^{[1
]}

ROESKY, HW ^{[1
]}

机构：

[1] UNIV GOTTINGEN, INST ANORGAN CHEM, TAMMANNSTR 4, W-3400 GOTTINGEN, GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1993年 / 48卷 / 05期

关键词：

MANGANESE COMPLEXES; X-RAY;

D O I：

10.1515/znb-1993-0508

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of Mn(CF3COO)2 (1) with N,N,N',N'-tetramethylethylenediamine (tmen), 2,2'-bipyridine (bipy) and triethanolamine (tea) yield three new mononuclear coordination compounds: trans-[Mn(tmen)2(CF3COO)2] (2), cis-[Mn(bipy)2(CF3COO)2] (3), and [Mn(tea)2](CF3COO)2 (4). The X-ray structures of the compounds 2, 3, and 4 are described. The seven-coordination of the manganese(II) ion in 4, as well as the inequivalency of the two tea molecules coordinated to Mn(II) make this compound unique.

引用

页码：591 / 597

页数：7

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