STUDIES ON POLYOXO-METALATES AND POLYPEROXO-METALATES .1. TETRAMERIC HETEROPOLYPEROXOTUNGSTATES AND HETEROPOLYPEROXOMOLYBDATES

被引：146

作者：

DENGEL, AC ^{[1
]}

GRIFFITH, WP ^{[1
]}

PARKIN, BC ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,INORGAN CHEM LABS,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 18期

关键词：

D O I：

10.1039/dt9930002683

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New heteropolyperoxometalates of the type R3[XO4{MO(O2)2}4] [R = N(C6H13)4+, N(PPh3)2+ or 1/3[Co(en)3]3+ (en = ethane-1.2-diamine); X = P or As; M = Mo or W] have been characterized by IR, Raman and where appropriate P-31 NMR spectroscopy. Epoxidation of cyclic and linear alkenes by these species with H2O2 as co-oxidant has been studied; [AsO4{WO(O2)2}4]3- was found to be the most effective. The oxidation of alcohols by [PO4{WO(O2)2}4]3- with H2O2 has been investigated.

引用

页码：2683 / 2688

页数：6

共 28 条

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