ELECTRON-DONORS AND CYANOIMIDAZOLE ACCEPTORS - CYCLIC VOLTAMMETRY AND MOLECULAR ORBITAL STUDY

被引：18

作者：

ALLAN, DS

BERGSTROM, DF

RASMUSSEN, PG

机构：

[1] UNIV MICHIGAN,DEPT CHEM & MACROMOLEC SCI,ANN ARBOR,MI 48109

[2] UNIV MICHIGAN,ENGN PROGRAM,ANN ARBOR,MI 48109

来源：

SYNTHETIC METALS | 1988年 / 25卷 / 02期

关键词：

ELECTRONS - Transport Properties - SALTS;

D O I：

10.1016/0379-6779(88)90349-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Voltammetric measurements on a series of cyanoimidazoles and their metal complexes are reported and compared with those for various donors and acceptors measured under the same conditions. LUMO (Lowest Unoccupied Molecular Orbitals) energies from extended Huckel calculations correlate well with reduction potentials of cyanoimidazoles. Extended Huckel calculations also give insights into the interaction of the metal complexes of tetracyanobiimidazole and the nature of molecular stacking.

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页码：139 / 155

页数：17

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