MOLECULAR-HYDROGEN COMPLEXES IN CATALYTIC REACTIONS - REACTIVITY OF NEUTRAL TRANSITION-METAL POLYHYDRIDES IN THE CATALYTIC TRANSFER HYDROGENATION OF KETONES

被引：22

作者：

LIN, YR

ZHOU, YF

机构：

[1] Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai, 200032

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 381卷 / 01期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/0022-328X(90)85455-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Transition metal polyhydrides are effective catalysts for the reduction of ketones by hydrogen transfer from 2-propanol at room temperature. The difference in the reactivity between RuH4(PPh3)3 and RuH2(PPh3)4 is discussed. © 1990.

引用

页码：135 / 138

页数：4

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