CONVENIENT SYNTHESES OF CHEVREL PHASE-COMPOUNDS FROM SOLUBLE SULFIDE PRECURSORS UNDER FLOWING HYDROGEN ATMOSPHERE

被引：30

作者：

RABILLERBAUDRY, M

SERGENT, M

CHEVREL, R

机构：

[1] Université de Rennes-Beaulieu, U.R.A. C.N.R.S. no 254, Laboratoire de Chimie Minérale B, 35042 Rennes Cédex, Avenue de General Leclerc

来源：

MATERIALS RESEARCH BULLETIN | 1991年 / 26卷 / 06期

关键词：

CHEVREL PHASE COMPOUNDS;

D O I：

10.1016/0025-5408(91)90192-O

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

New methods to synthesize Chevrel phases compounds have been performed. The starting materials can be mixture of polythiomolybdates and salts of metal (copper, lead). In all cases, the intermediate of the reaction is a mixture of molybdenum disulfide and the appropriate metal. Then, these bulky syntheses are used as model in order to synthesize Chevrel phases supported on alumina. So, far the the time, we prepare such supported compounds, that will probably find application in heterogenous catalysis reactions.

引用

页码：519 / 526

页数：8

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