CATIONIC RHODIUM CYCLOOCTADIENE COMPLEXES WITH NITRILE LIGANDS

被引：33

作者：

USON, R

ORO, LA

ARTIGAS, J

SARIEGO, R

机构：

[1] Department of Inorganic Chemistry, University of Zaragoza, Zaragoza

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)87796-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and properties ;of complexes of the general formula [Rh(COD)L2]ClO4 (COD = 1,5-cyclooctadiene; L = monodentate nitrile group or LL = bidentate nitrile group) and of mixed complexes of the type [Rh(COD)LP(p-RC6H4)3]A (P = triorganophosphine; A = ClO4- or BPh4-; R = F, H, CH3, OCH3) are described. These complexes react with molecular hydrogen to form species which catalyze the hydrogenation of terminal and cyclic olefins. © 1979.

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页码：65 / 72

页数：8

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