FUNCTIONAL DOPANTS IN CONDUCTING POLYMERS

被引：23

作者：

WALTON, DJ ^{[1
]}

HALL, CE ^{[1
]}

CHYLA, A ^{[1
]}

机构：

[1] WROCLAW TECH UNIV,INST INORGAN & PHYS CHEM,PL-50370 WROCLAW,POLAND

来源：

SYNTHETIC METALS | 1991年 / 45卷 / 03期

关键词：

D O I：

10.1016/0379-6779(91)91791-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Polypyrroles have been prepared containing large complex functionalized dopant anions that convey their functionality to the polymer; preparation conditions have been established for the production of bulk free-standing films. The redox properties of 1,1'-ferrocenedisulfonate-doped polypyrrole show stabilization of iron(II) in the polymer, while the absorption spectrum of tetrasulfonatophthalocyanine-doped polypyrroles are influenced by the presence of the dye; polypyrrole doped with tetrasulfonated dibenzo-18-crown-6 shows affinity for potassium ions in solution. In addition, similarities on polymer redox voltammetry for polymers containing all these dopants suggest the occurrence of a common redox process.

引用

页码：363 / 371

页数：9

共 17 条

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