RATE CONSTANTS FOR THE REACTIONS OF PRIMARY ALKYL RADICALS WITH SMI2 IN THF/HMPA

被引：110

作者：

HASEGAWA, E ^{[1
]}

CURRAN, DP ^{[1
]}

机构：

[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(00)60760-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first bimolecular rate constants for the reduction of a primary alkyl radical by SmI2 were obtained by using a competitive hexenyl radical clock. Rate constants varied from 5 x 10(5) to 7 x 10(6) M-1 s-1, depending on the amount of HMPA present.

引用

页码：1717 / 1720

页数：4

共 16 条

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