SYNTHESIS AND CHARACTERIZATION OF WATER-SWELLABLE ALPHA,BETA-POLYASPARTHYDRAZIDE DERIVATIVES

被引:19
作者
GIAMMONA, G [1 ]
PITARRESI, G [1 ]
TOMARCHIO, V [1 ]
SPADARO, G [1 ]
机构
[1] UNIV PALERMO,DIPARTIMENTO INGN CHIM PROC & MAT,I-90128 PALERMO,ITALY
关键词
CROSS-LINKED ALPHA; BETA-POLYASPARTHYDRAZIDE; HYDROGELS; SWELLABLE MICROMATRICES;
D O I
10.1007/BF00664733
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of a new crosslinked polymer by reaction of alpha, beta-polyasparthydrazide and glutaraldehyde is reported. Different crosslinking degrees were obtained by varying the ratio between the aldehyde and the starting polymer. The crosslinked polymer was characterized by water swelling tests and thermal analysis. In particular, the crosslinking density and its effects on the glass transition temperature of the material were studied. Finally, the microstructure of the obtained polymer was observed using scanning electron microscopy.
引用
收藏
页码:1637 / 1641
页数:5
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