A MODIFICATION OF BLOCK-WALKERS REACTION FIELD FOR A NONIDEAL DIPOLE

被引:1
作者
ABE, T
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D O I
10.1246/bcsj.67.2913
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Block-Walker's reaction field derived from considering a distance-dependent relative permittivity for a point dipole in the center of a spherical cavity is modified for a non-ideal dipole directed along the radius vector. The reaction field energies of the non-ideal dipole for two special cases are compared with those of the point dipole in the center of the cavity. Thus, the validity of approximation of Block-Walker's reaction field is investigated.
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页码:2913 / 2916
页数:4
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