THE USE OF 3-ALKYL-2,4-DIKETOPIPERIDINES IN ASYMMETRIC MICHAEL ADDITIONS

被引：8

作者：

AMBROISE, L

CHASSAGNARD, C

REVIAL, G

DANGELO, J

机构：

[1] Unité de Chimie Organique Associée au CNRS, ESPCI, 75231 Paris Cedex 05

来源：

TETRAHEDRON-ASYMMETRY | 1991年 / 2卷 / 06期

关键词：

2,4-DIKETOPIPERIDINES; CHIRAL ENAMINES; ASYMMETRIC MICHAEL ADDITION; IMINE-REVERSIBLE-ENAMINE TAUTOMERISM; INDOLE ALKALOIDS;

D O I：

10.1016/S0957-4166(00)82163-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral enamine 12, derived from 2,4-diketopiperidine 11 added to methyl acrylate, leading, after hydrolytic work-up to adduct 15 (94 % stereoselectivity).

引用

页码：407 / 410

页数：4

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