STEREOSELECTION IN THERMAL ASYMMETRIC DIELS-ALDER REACTIONS - ELECTRONIC VS STERIC EFFECTS

被引：26

作者：

STAMMEN, B ^{[1
]}

BERLAGE, U ^{[1
]}

KINDERMANN, R ^{[1
]}

KAISER, M ^{[1
]}

GUNTHER, B ^{[1
]}

SHELDRICK, WS ^{[1
]}

WELZEL, P ^{[1
]}

ROTH, WR ^{[1
]}

机构：

[1] RUHR UNIV BOCHUM,FAK CHEM,POSTFACH 102148,W-4630 BOCHUM,GERMANY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 24期

关键词：

D O I：

10.1021/jo00050a037

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Experimental evidence was found for an electronic contribution favoring the cisoid conformation of alpha,beta-unsaturated carbonyl compounds in thermal Diels-Alder transition states.

引用

页码：6566 / 6575

页数：10

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