MASS-TRANSPORT IN THE PRESENCE OF INTERNAL DEFECT REACTIONS - CONCEPT OF CONSERVATIVE ENSEMBLES .2. EVALUATION OF ELECTROCHEMICAL TRANSPORT MEASUREMENTS

被引：41

作者：

MAIER, J

机构：

[1] Max-Planck-Institut fur Festkörperforschung, Stuttgart

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 1993年 / 76卷 / 05期

关键词：

D O I：

10.1111/j.1151-2916.1993.tb03744.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

It is shown that in the general case of a defective solid, where the ionic point defects can change their valence states, the evaluation formulas of well-known-electrochemical techniques (such as concentration cell experiments, Wagner-Hebb method, chemical and electrochemical polarization and relaxation) have to be modified. The generalized relationships are derived.

引用

页码：1218 / 1222

页数：5

共 23 条

[1] Carslaw HS, 1988, CONDUCTION HEAT SOLI
[2] Crank J., 1970, MATH DIFFUSION
[3] DUDLEY FJ, 1980, J SOLID STATE CHEM, V10, P233
[4] HAUFFE K, 1966, REAKTIONEN FESTEN ST
[5] ELECTRICAL CONDUCTIVITY OF SILVER SULFIDE
HEBB, MH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1952, 20 (01) : 185 - 190
[6] Heyne L., 1977, SOLID ELECTROLYTES, P169
[7] Kroger F.A., 1973, CHEM IMPERFECT CRYST
[8] THEORETICAL TREATMENT OF THE DIFFUSION COUPLED WITH REACTION, APPLIED TO THE EXAMPLE OF A BINARY SOLID COMPOUND-MX
MAIER, J
SCHWITZGEBEL, G
[J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1982, 113 (02): : 535 - 547
[9] MASS-TRANSPORT IN THE PRESENCE OF INTERNAL DEFECT REACTIONS - CONCEPT OF CONSERVATIVE ENSEMBLES .1. CHEMICAL DIFFUSION IN PURE COMPOUNDS
MAIER, J
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1993, 76 (05) : 1212 - 1217
[10] CONDUCTIVITY IN AN ACTIVITY GRADIENT
MAIER, J
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1985, 46 (02) : 197 - 200

← 1 2 3 →