SYNTHESIS OF METHYL (D-GLYCOPYRANOSYL AZIDE)URONATES

被引：68

作者：

GYORGYDEAK, Z ^{[1
]}

THIEM, J ^{[1
]}

机构：

[1] LAJOS KOSSUTH UNIV,DEPT ORGAN CHEM,H-4010 DEBRECEN,HUNGARY

来源：

CARBOHYDRATE RESEARCH | 1995年 / 268卷 / 01期

关键词：

(D-GLYCOPYRANOSYL AZIDE)URONATES; GLYCOSYL AZIDES; NAOCL TEMPO OXIDATION;

D O I：

10.1016/0008-6215(94)00313-5

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Sodium hypochlorite oxidation catalysed by 2,2,6,6,-tetramethylpiperidine 1-oxide (TEMPO) is shown to be a mild and efficient approach to the title uronates. In the gluco, galacto, allo, and 2-acetamido-2-deoxy-gluco series, the corresponding beta- or alpha- and beta-glycosyl azides could be smoothly oxidised and alternative preparations are compared to this access.

引用

页码：85 / 92

页数：8

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