Calculation of the isotope effect on the triplet lifetime of partially deuterated naphthaleness

被引：27

作者：

Henry, B. R. ^{[1
]}

Siebrand, W. ^{[1
]}

机构：

[1] Natl Res Council Canada, Div Pure Chem, Ottawa, ON, Canada

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 3卷 / 05期

基金：

英国医学研究理事会;

关键词：

D O I：

10.1016/0009-2614(69)80244-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Differences in triplet lifetime between alpha and beta deuterated naphthalenes are calculated in good agreement with experiment. The calculation is based on vibronic spin-orbit coupling involving sigma pi* and pi sigma* states together with CH out-of-plane bending modes.

引用

页码：327 / 328

页数：2

共 16 条

[1] INTERNAL CONVERSION IN AROMATIC AND N-HETEROAROMATIC MOLECULES
BYRNE, JP
MCCOY, EF
ROSS, IG
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1965, 18 (10) : 1589 - &
[2] FREEMAN DE, 1960, SPECTROCHIM ACTA, V16, P1393
[3] ANHARMONICITY IN POLYATOMIC MOLECULES . CH-STRETCHING OVERTONE SPECTRUM OF BENZENE
HENRY, BR
SIEBRAND, W
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (12) : 5369 - &
[4] Spin-orbit coupling in aromatic hydrocarbons. The radiative triplet lifetime of naphthalene
Henry, Bryan R.
Siebrand, Willem
[J]. CHEMICAL PHYSICS LETTERS, 1969, 3 (02) : 90 - 92
[5] EFFECT OF DEUTERATION OF DURENE ON LIFETIME OF PHOSPHORESCENT TRIPLET STATE OF NAPHTHALENE IN A DURENE HOST CRYSTAL
HIROTA, N
HUTCHISON, CA
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (05) : 1561 - +
[6] EFFECT OF PARTIAL DEUTERATION AND TEMPERATURE ON TRIPLET-STATE LIFETIMES
LIN, SH
BERSOHN, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 48 (06) : 2732 - &
[7] RATE OF INTERCONVERSION OF ELECTRONIC AND VIBRATIONAL ENERGY
LIN, SH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (10) : 3759 - &
[8] LUTHER H, 1962, Z ELEKTROCHEM, V66, P546
[9] Martin T., UNPUB
[10] THEORY OF ELECTRONIC ENERGY RELAXATION IN SOLID PHASE
ROBINSON, GW
FROSCH, RP
[J]. JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (09) : 1962 - &

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