THIOALDEHYDE S-OXIDE (MONOSUBSTITUTED SULFINES) FROM THIOACYLSILANE S-OXIDES - SYNTHESIS AND FLUORINE-INDUCED AND ACID-INDUCED Z/E ISOMERIZATION .2.

被引：34

作者：

BARBARO, G ^{[1
]}

BATTAGLIA, A ^{[1
]}

GIORGIANNI, P ^{[1
]}

BONINI, BF ^{[1
]}

MACCAGNANI, G ^{[1
]}

ZANI, P ^{[1
]}

机构：

[1] UNIV BOLOGNA,DEPARTIMENTO CHIM ORGAN,I-40136 BOLOGNA,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 12期

关键词：

D O I：

10.1021/jo00299a012

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic and aliphatic, not enethiolizable, thioaldehyde S-oxides (monosubstituted sulfines) are obtained from stereospecific fluorodesilylation of the corresponding thioacylsilane S-oxides with retention of configuration. A detailed investigation on the mechanism of the desilylation, as well as of the acid and fluoride ion induced Z/E interconversion has been performed. © 1990, American Chemical Society. All rights reserved.

引用

页码：3744 / 3748

页数：5

共 28 条

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