CHIRAL TOLUENE-2,ALPHA-SULTAM AUXILIARIES - ASYMMETRIC DIELS-ALDER REACTIONS OF N-ENOYL DERIVATIVES

被引：100

作者：

OPPOLZER, W

WILLS, M

KELLY, MJ

SIGNER, M

BLAGG, J

机构：

[1] Département de Chimie Organique, Université de Genève

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)97793-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric, RmAlCln mediated Diels-Alder reactions of 1,3-dienes to N-enoyl derivatives 4 and 9 of (R)-methyl-, (R,S)-t-butyl-, α,α-dimethylbenzyl-, benzyl and (S)-methyl-toluene-2,α-sultams 3 as well as to N-enoyl derivatives 15 of (R)-2,3-dihydro-3-methylisoindolinone 14 are described. © 1990.

引用

页码：5015 / 5018

页数：4

共 16 条

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[6] BORNANESULTAM-DIRECTED ASYMMETRIC-SYNTHESIS OF CRYSTALLINE, ENANTIOMERICALLY PURE SYN ALDOLS
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[7] ASYMMETRIC DIELS-ALDER REACTIONS - X-RAY CRYSTAL-STRUCTURE ANALYSIS OF [N-((E)-BUT-2-ENOYL)BORNANE-10,2-SULTAM]TETRACHLOROTITANIUM
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[8] CAMPHOR-DERIVED N-ACRYLOYL AND N-CROTONOYL SULTAMS - PRACTICAL ACTIVATED DIENOPHILES IN ASYMMETRIC DIELS-ALDER REACTIONS
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[9] ENANTIOSELECTIVE SYNTHESIS AND ABSOLUTE-CONFIGURATION OF (-)-PULOUPONE BY ASYMMETRIC INTRAMOLECULAR DIELS-ALDER REACTION
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