A MOLECULAR MOTOR

被引:6
作者
CLOUGH, S
HORSEWILL, AJ
JOHNSON, MR
SUTCLIFFE, JH
TOMSAH, IBI
机构
[1] Department of Physics, University Park, Nottingham
来源
EUROPHYSICS LETTERS | 1995年 / 29卷 / 02期
关键词
D O I
10.1209/0295-5075/29/2/011
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Experiments are described in which the rotation of methyl groups in solids at helium temperatures is driven using external magnetic fields. The orientation of the nuclear magnetic dipoles is caused to oscillate in synchronism with coherent tunnelling rotation, switching time-dependent internal-magnetic-field gradients due to the dipole-dipole interaction to produce a small steady torque. The resulting change in the frequency of tunnelling, of the order of 150 kHz, is detected by field cycling NMR.
引用
收藏
页码:169 / 173
页数:5
相关论文
共 6 条
[1]   THE SPECTRUM OF ROTATING WAVEPACKETS OF HINDERED METHYL-GROUPS [J].
CLOUGH, S ;
HORSEWILL, AJ ;
ALSANOOSI, AM ;
BARLOW, MJ ;
JOHNSON, MR .
CHEMICAL PHYSICS LETTERS, 1993, 211 (06) :637-642
[2]   MOLECULAR TUNNELING MEASURED BY DIPOLE-DIPOLE - DRIVEN NUCLEAR MAGNETIC-RESONANCE [J].
CLOUGH, S ;
HORSEWILL, AJ ;
MCDONALD, PJ ;
ZELAYA, FO .
PHYSICAL REVIEW LETTERS, 1985, 55 (17) :1794-1796
[3]   ROTATIONAL QUANTIZATION OF METHYL-GROUPS IN A ROTATING-FRAME [J].
CLOUGH, S ;
HORSEWILL, AJ ;
JOHNSON, MR ;
SUTCLIFFE, JH ;
TOMSAH, IBI .
MOLECULAR PHYSICS, 1994, 81 (04) :975-990
[4]  
CLOUGH S, 1987, CHEM PHYS LETT, V142, P209
[6]   NUCLEAR MAGNETIC RESONANCE SATURATION AND ROTARY SATURATION IN SOLIDS [J].
REDFIELD, AG .
PHYSICAL REVIEW, 1955, 98 (06) :1787-1809