PERFLUOROHEXANE AS A NOVEL REACTION MEDIUM FOR BROMINATION REACTIONS

被引：20

作者：

PEREIRA, SM ^{[1
]}

SAVAGE, GP ^{[1
]}

SIMPSON, GW ^{[1
]}

机构：

[1] CSIRO,DIV CHEM & POLYMERS,CLAYTON,VIC 3169,AUSTRALIA

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 07期

关键词：

D O I：

10.1080/00397919508012663

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Perfluorohexane is shown to be a good alternative to carbon tetrachloride as a non-toxic, non-ozone-depleting, inert reaction medium for bromination reactions. Yields of brominated products were nearly quantitative and the reaction work-up was easier.

引用

页码：1023 / 1026

页数：4

共 9 条

[1]

ABBOTT TW, 1943, ORG SYNTH, V2, P270

[2] FLASH-PHOTOLYSIS OF CHROMIUM HEXACARBONYL IN PERFLUOROCARBON SOLVENTS - OBSERVATION OF A HIGHLY REACTIVE CHROMIUM PENTACARBONYL [J].