GOLD(I) COMPLEXES WITH N-DONOR LIGANDS .1. SYNTHESIS OF COMPLEXES [AU(PPH(3))L](+) (L=PRIMARY, SECONDARY OR TERTIARY AMINE) - CRYSTAL-STRUCTURE OF [AU(PPH(3))(NME(3))][CLO4]CENTER-DOT-CH2CL2

被引：28

作者：

VICENTE, J ^{[1
]}

CHICOTE, MT ^{[1
]}

GUERRERO, R ^{[1
]}

JONES, PG ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1995年 / 08期

关键词：

D O I：

10.1039/dt9950001251

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 1:1 reaction of [Au(acac)(PPh(3))] (Hacac = acetylacetone) with ammonium salts [HL]X (X = CF3SO3, L = 2-nitroaniline, 4-methoxyaniline. NHPh(2) or NHEt(2); X = ClO4, L = NMe(3)) in diethyl ether gave complexes [Au(PPh(3))L]X and acety]acetone. The crystal structure of [Au(PPh(3))(NMe(3))][ClO4] was determined; orthorhombic, space group P2(1)2(1)2(1), a = 9.498(2), b = 10.322(2) c = 26.154(4) Angstrom, wR(F-2) 0.091. The gold atom is linearly co-ordinated to both ligands [AU-P 2.231 (2). Au-N 2.108(7) Angstrom, P-Au-N 179.3(2)degrees] and no intermolecular Au..Au contacts exist.

引用

页码：1251 / 1254

页数：4

共 37 条

[1] HEXANUCLEAR GOLD(I) COMPLEX - [((PH(3)PAU)(2)C(PPH(2)AUPPH(2)))(2)](CLO4)(2) [J].

FERNANDEZ, EJ ;

GIMENO, MC ;

JONES, PG ;

LAGUNA, A ;

LAGUNA, M ;

LOPEZDELUZURIAGA, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (01) :87-88

[2] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[3]

GEARY WJ, 1981, COORDIN CHEM REV, V7, P81

[4] METAL BETA-DIKETONE COMPLEXES .6. SOME BETA-DIKETONE COMPLEXES OF COPPER(I), SILVER(I), AND GOLD(I) [J].

GIBSON, D ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (03) :367-&

[5] REACTIONS OF [AU(ACAC)PPH3] WITH DIPHOSPHINE DERIVATIVES - DIFFERENT COORDINATION MODES OF GOLD TO THE LIGAND SYSTEMS - X-RAY STRUCTURE OF [SPPH2C(AUPPH3)2PPH2CH(AUPPH3)COOME]CLO4 AND [AU5(C6F5)((SPPH2)2C-]2(PPH3)] [J].

GIMENO, MC ;

LAGUNA, A ;

LAGUNA, M ;

SANMARTIN, F ;

JONES, PG .

ORGANOMETALLICS, 1993, 12 (10) :3984-3991

[6] REACTIONS OF [AU(ACAC)PPH3] WITH DIPHOSPHINE DERIVATIVES - DIFFERENT COORDINATION MODES OF GOLD TO THE LIGAND SYSTEMS - X-RAY STRUCTURE OF [SPPH2C-(AUPPH3)2PPH2CH(AUPPH3)COOME]CLO4 AND [AU5-(C6F5)((SPPH2)2C)2(PPH3)) (VOL 12, PG 3984, 1993) [J].

GIMENO, MC ;

LAGUNA, A ;

LAGUNA, M ;

SANMARTIN, F ;

JONES, PG .

ORGANOMETALLICS, 1994, 13 (04) :1538-1538

[7] GILDING PRIMARY AMINES - FORMATION OF ORGANOTRIS(TRIPHENYLPHOSPHINEAURIO)AMMONIUM TETRAFLUOROBORATES [AUPPH3)3-NR]+BF4- - CRYSTAL-STRUCTURES WHERE R= BU(T) OR C6H11 [J].

GROHMANN, A ;

RIEDE, J ;

SCHMIDBAUR, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, :783-787

[8]

GROHMANN A, 1992, Z NATURFORSCH B, V47, P1255

[9] IMIDO-GOLD CLUSTERS - SYNTHESIS AND MAGNETIC-RESONANCE SPECTROSCOPY OF GILDED DIAMINES [J].

GROHMANN, A ;

SCHMIDBAUR, H .

INORGANIC CHEMISTRY, 1992, 31 (16) :3378-3380

[10]

GROHMANN A, 1990, NATURE, V35, P140

← 1 2 3 4 →