REGIOSELECTIVE ELECTROPHILIC ADDITIONS TO 2-ALKOXY-7-OXABICYCLO[2.2.1]HEPT-5-ENE AND 2-ALKOXYMETHYL-7-OXABICYCLO[2.2.1]HEPT-5-ENE DERIVATIVES

被引：21

作者：

ARJONA, O ^{[1
]}

DELAPRADILLA, RF ^{[1
]}

PITAROMERO, I ^{[1
]}

PLUMET, J ^{[1
]}

VISO, A ^{[1
]}

机构：

[1] CSIC,INST QUIM ORGAN GEN,E-28006 MADRID,SPAIN

来源：

TETRAHEDRON | 1990年 / 46卷 / 24期

关键词：

D O I：

10.1016/S0040-4020(01)81476-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The influence of the stereochemistry at C-2 on the selectivity of the reaction between PhSeBr and 2-alkoxymethyl substituted oxanorbornenes has been studied. All endo isomers displayed complete regio- and stereocontrol with incorporation of the electrophile on C-5. © 1990.

引用

页码：8199 / 8206

页数：8

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